Charlie James was already 30 years old when she decided to join the adult film business. She became an active performer from 2008 up until 2011. You can catch Charlie perform in 18 different porn movies during her stay in the business. One of her early works was 110% Natural 17 distributed by Red Light District. Charlie James also did an all-female film titled Lesbian Seductions 24 and shared the screen with Vannah Sterling, Totally Tabitha and Shayne Ryder. Pure Play Media also featured her in their porn series titled My First Sex Teacher where she was seen enjoying a hot facial cum shot scene. Adult film director John Janeiro worked with her when they shot the erotic film Cream Pie Squad 17 in 2011. The other works of Charlie James were in the porn movies Broke Down Bitches 6, 110% Natural 17, My First Sex Teacher 23 and Top Heavy Tarts 10.